First-pass extracted concept

nonenzymatic biosynthetic reactions

Candidate: concept label1 source documents3 linked claims

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Evidence Snippets

there are cases in which the inherent chemical reactivity of metabolic intermediates and substrates evades the involvement of enzymes

Evidence 1Source 1DOI PubMedprovenance

Supporting Sources

Source 1review2022Chemical ReviewsDOI PubMed

1 evidence snippet 3 linked claims Claim 1 Claim 2 Claim 3

Linked Claims

Claim 1challenge statementsupports2022Source 1DOI PubMed

Nonenzymatic biosynthetic reactions are difficult to characterize because of their reactivity and their occlusion within the cellular environment.

Claim 2mechanistic summarysupports2022Source 1DOI PubMed

Nonenzymatic biosynthetic steps can arise from the inherent chemical reactivity of metabolic intermediates and substrates without enzyme involvement.

Claim 3review scope classificationsupports2022Source 1DOI PubMed

The review classifies nonenzymatic natural product biosynthetic reactions into four categories: intramolecular, multicomponent, tailoring, and light-induced reactions.