Source 1primary paper2020ChemCatChem
Toolkit/photoswitchable phosphines
photoswitchable phosphines
Also known as: photoswitchable catalysts based on phosphorus ligands
Taxonomy: Mechanism Branch / Component. Workflows sit above the mechanism and technique branches rather than replacing them.
Summary
Photoswitchable catalysts based on phosphorus ligands have been overlooked so far... including synthetic approaches to photoswitchable phosphines and their transition metal complexes.
Usefulness & Problems
No literature-backed usefulness or problem-fit explainer has been materialized for this record yet.
Taxonomy & Function
Primary hierarchy
Mechanism Branch
Component: A low-level protein part used inside a larger architecture that realizes a mechanism.
Mechanisms
light-dependent modulation of catalytic activitylight-dependent tuning of chemoselectivitylight-dependent tuning of enantioselectivityphotoswitchingTechniques
No technique tags yet.
Target processes
No target processes tagged yet.
Input: Light
Validation
Cell-freeBacteriaMammalianMouseHumanTherapeuticIndep. Replication
Supporting Sources
Ranked Claims
Photoswitchable phosphines can regulate catalytic activity using irradiation as a non-invasive external stimulus.
This survey demonstrates that both regulation of the catalytic activity and tuning of the chemo‐ and enantioselectivity can be achieved using irradiation as a non‐invasive external stimulus.
Photoswitchable phosphines can tune chemoselectivity and enantioselectivity under irradiation.
This survey demonstrates that both regulation of the catalytic activity and tuning of the chemo‐ and enantioselectivity can be achieved using irradiation as a non‐invasive external stimulus.
The reviewed applications of photoswitchable phosphines include rhodium, palladium, gold, ruthenium, and copper catalysis.
This review surveys the current knowledge in the field, including synthetic approaches to photoswitchable phosphines and their transition metal complexes, and applications in rhodium, palladium, gold, ruthenium and copper catalysis.
Approval Evidence
1 source3 linked approval claimsfirst-pass slug photoswitchable-phosphines
Photoswitchable catalysts based on phosphorus ligands have been overlooked so far... including synthetic approaches to photoswitchable phosphines and their transition metal complexes.
Source:
capabilitysupports
Photoswitchable phosphines can regulate catalytic activity using irradiation as a non-invasive external stimulus.
This survey demonstrates that both regulation of the catalytic activity and tuning of the chemo‐ and enantioselectivity can be achieved using irradiation as a non‐invasive external stimulus.
Source:
capabilitysupports
Photoswitchable phosphines can tune chemoselectivity and enantioselectivity under irradiation.
This survey demonstrates that both regulation of the catalytic activity and tuning of the chemo‐ and enantioselectivity can be achieved using irradiation as a non‐invasive external stimulus.
Source:
scopesupports
The reviewed applications of photoswitchable phosphines include rhodium, palladium, gold, ruthenium, and copper catalysis.
This review surveys the current knowledge in the field, including synthetic approaches to photoswitchable phosphines and their transition metal complexes, and applications in rhodium, palladium, gold, ruthenium and copper catalysis.
Source:
Comparisons
No literature-backed comparison notes have been materialized for this record yet.
Ranked Citations
- 1.