Source 1review2021Chemical Science
Toolkit/multicomponent multifunctional host-guest complex
multicomponent multifunctional host-guest complex
Taxonomy: Mechanism Branch / Architecture. Workflows sit above the mechanism and technique branches rather than replacing them.
Summary
We discuss first examples resulting from a combination of both principles, namely multicomponent multifunctional host-guest complexes, and their potential in application in areas such as sensing, catalysis, and photo-redox systems.
Usefulness & Problems
Why this is useful
These complexes combine multicomponent assembly and multifunctionality in host-guest systems. The review highlights them as early examples of merging both design principles.; combining host-guest behavior with multiple functions; sensing applications; catalysis applications; photo-redox applications
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These complexes combine multicomponent assembly and multifunctionality in host-guest systems. The review highlights them as early examples of merging both design principles.
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combining host-guest behavior with multiple functions
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sensing applications
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catalysis applications
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photo-redox applications
Problem solved
They address the challenge of building host-guest assemblies that do more than simple binding by integrating multiple functions. The review links this to sensing, catalysis, and photo-redox use cases.; integrating multiple functional principles within one host-guest assembly
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They address the challenge of building host-guest assemblies that do more than simple binding by integrating multiple functions. The review links this to sensing, catalysis, and photo-redox use cases.
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integrating multiple functional principles within one host-guest assembly
Problem links
integrating multiple functional principles within one host-guest assembly
LiteratureThey address the challenge of building host-guest assemblies that do more than simple binding by integrating multiple functions. The review links this to sensing, catalysis, and photo-redox use cases.
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They address the challenge of building host-guest assemblies that do more than simple binding by integrating multiple functions. The review links this to sensing, catalysis, and photo-redox use cases.
Taxonomy & Function
Primary hierarchy
Mechanism Branch
Architecture: A reusable architecture pattern for arranging parts into an engineered system.
Mechanisms
confinement-enabled reactivityhost-guest recognitionphotoswitch-based stimulus controlself-assemblyTechniques
No technique tags yet.
Target processes
recombinationInput: Light
Implementation Constraints
cofactor dependency: cofactor requirement unknownencoding mode: genetically encodedimplementation constraint: context specific validationimplementation constraint: spectral hardware requirementoperating role: regulator
The abstract supports that they depend on both selective multicomponent assembly and functional implementation within the host system. Specific guest classes or assay formats are not provided.; requires combining functionalized cage design with multicomponent assembly strategies
The abstract does not show that these systems are mature or broadly optimized. It only supports that first examples exist and have application potential.; the abstract describes first examples, implying the area is still early
Validation
Cell-freeBacteriaMammalianMouseHumanTherapeuticIndep. Replication
Supporting Sources
Ranked Claims
Multicomponent multifunctional host-guest complexes are presented as early examples with potential applications in sensing, catalysis, and photo-redox systems.
We discuss first examples resulting from a combination of both principles, namely multicomponent multifunctional host-guest complexes, and their potential in application in areas such as sensing, catalysis, and photo-redox systems.
Combining several functionalities within the same assembly without creating statistical mixtures requires sophisticated assembly strategies.
Combining several functionalities without creating statistical mixtures, however, requires a toolbox of sophisticated assembly strategies.
Dedicated functionalities such as catalytic centres or photoswitches have been implemented in coordination cages to enable stimuli control and expanded function.
Recently, the field has made big steps forward by implementing dedicated functionality, e.g. catalytic centres or photoswitches to allow stimuli control.
Self-assembled coordination cages have attracted growing attention because their nano-scale cavities enable host functions such as selective recognition and confined reaction environments.
cages, with particularly the latter ones catching growing attention, owing to their nano-scale cavities. Assemblies serving as hosts allow application as selective receptors, confined reaction environments and more.
Approval Evidence
1 source2 linked approval claimsfirst-pass slug multicomponent-multifunctional-host-guest-complex
We discuss first examples resulting from a combination of both principles, namely multicomponent multifunctional host-guest complexes, and their potential in application in areas such as sensing, catalysis, and photo-redox systems.
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application potentialsupports
Multicomponent multifunctional host-guest complexes are presented as early examples with potential applications in sensing, catalysis, and photo-redox systems.
We discuss first examples resulting from a combination of both principles, namely multicomponent multifunctional host-guest complexes, and their potential in application in areas such as sensing, catalysis, and photo-redox systems.
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design challengesupports
Combining several functionalities within the same assembly without creating statistical mixtures requires sophisticated assembly strategies.
Combining several functionalities without creating statistical mixtures, however, requires a toolbox of sophisticated assembly strategies.
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Comparisons
Source-stated alternatives
The review frames these complexes as a combination of two earlier directions: functionalized cages and selectively formed heteroleptic structures.
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The review frames these complexes as a combination of two earlier directions: functionalized cages and selectively formed heteroleptic structures.
Source-backed strengths
presented as combining functional implementation with multicomponent assembly
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presented as combining functional implementation with multicomponent assembly
Compared with heteroleptic coordination cage
The review frames these complexes as a combination of two earlier directions: functionalized cages and selectively formed heteroleptic structures.
Shared frame: source-stated alternative in extracted literature
Strengths here: presented as combining functional implementation with multicomponent assembly.
Relative tradeoffs: the abstract describes first examples, implying the area is still early.
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The review frames these complexes as a combination of two earlier directions: functionalized cages and selectively formed heteroleptic structures.
Ranked Citations
- 1.